Electrodeposition of Cu(In,Ga)Se2 Crystals on High-Density CdS Nanowire Arrays for Photovoltaic Applications

被引：35

作者：

Kwak, Woo-Chul ^{[1
]}

Han, Sung-Hwan ^{[2
]}

Kim, Tae Geun ^{[3
]}

Sung, Yun-Mo ^{[1
]}

机构：

[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea

[2] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

[3] Korea Univ, Dept Elect Engn, Seoul 136713, South Korea

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 12期

关键词：

FILM SOLAR-CELLS; CONDUCTIVE GLASS; GROWTH; MORPHOLOGY;

D O I：

10.1021/cg101157a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-density and single-crystalline CdS nanowires were grown on fluorine-doped tin oxide (FTO)/soda-lime glass substrates using Bi catalysts via the so-called solution liquid solid (SLS) mechanism Through a series of voltage loading steps, high-quality Cu(In,Ga)Se-2(CIGS) light absorption layers were electrochemically deposited on the CdS window layers and subsequently selonized at 400 degrees C to form photovoltaic cells Due to the one dimensionality and single crystallinity of the CdS nanowires, the carrier collection efficiency could be improved The resulting CIGS/CdS nanowire solar cells showed a light energy conversion efficiency of similar to 6 18% under AM 1 5 conditions (I = 100 mW/cm(2)), which is similar to 28 7% higher than that of the equivalent CIGS solar cells containing chemically deposited CdS thin film as a window layer

引用

页码：5297 / 5301

页数：5

共 21 条

[1] Nanotechnology: Wired for success [J].

Appell, D .

NATURE, 2002, 419 (6907) :553-555

[2] Nature of photovoltaic action in dye-sensitized solar cells [J].

Cahen, D ;

Hodes, G ;

Grätzel, M ;

Guillemoles, JF ;

Riess, I .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (09) :2053-2059

[3] Controlling growth chemistry and morphology of single-bath electrodeposited Cu(In,Ga)Se2 thin films for photovoltaic application [J].

Calixto, ME ;

Dobson, KD ;

McCandless, BE ;

Birkmire, RW .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (06) :G521-G528

[4]

Contreras MA, 1999, PROG PHOTOVOLTAICS, V7, P311, DOI 10.1002/(SICI)1099-159X(199907/08)7:4<311::AID-PIP274>3.0.CO

[5]

2-G

[6] Electrodeposition of CuIn1-xGaxSe2 precursor films:: optimization of film composition and morphology [J].

Fernández, AM ;

Bhattacharya, RN .

THIN SOLID FILMS, 2005, 474 (1-2) :10-13

[7] Epitaxial growth of very large grain bicrystalline Cu(In,Ga)Se2 thin films by a hybrid sputtering method [J].

Hall, A. J. ;

Hebert, D. ;

Lei, C. ;

Rockett, A. ;

Siebentritt, S. .

JOURNAL OF APPLIED PHYSICS, 2008, 103 (08)

[8] Low cost processing of CIGS thin film solar cells [J].

Kaelin, M ;

Rudmann, D ;

Tiwari, AN .

SOLAR ENERGY, 2004, 77 (06) :749-756

[9] Template-Free Liquid-Phase Synthesis of High-Density CdS Nanowire Arrays on Conductive Glass [J].

Kwak, Woo-Chul ;

Kim, Tae Geun ;

Lee, Wonjoo ;

Han, Sung-Hwan ;

Sung, Yun-Mo .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (04) :1615-1619

[10] Growth of CdS Nanorod-Coated TiO2 Nanowires on Conductive Glass for Photovoltaic Applications [J].

Lee, Jung-Chul ;

Kim, Tae Geun ;

Lee, Wonjoo ;

Han, Sung-Hwan ;

Sung, Yun-Mo .

CRYSTAL GROWTH & DESIGN, 2009, 9 (10) :4519-4523

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