Removal of arsenic and cadmium by akaganeite fixed-beds

被引:29
作者
Deliyanni, EA [1 ]
Bakoyannakis, DN [1 ]
Zouboulis, AI [1 ]
Peleka, E [1 ]
机构
[1] Aristotle Univ Thessaloniki, Sch Chem, Dept Chem Technol, GR-54006 Thessaloniki, Greece
关键词
akaganeite; adsorption; column; arsenic; cadmium;
D O I
10.1081/SS-120024714
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibility of using a packed-bed (in column configuration) of akaganeite to remove oxyanions like As(V) and cations like Cd from aqueous solutions was the aim of the present study. Synthesized..akaganeite was used in two forms, i.e., in fine powder (of nanocrystals) and in the form of grains (as granular). The main examined parameters were: 1) the quantity of sorbent in the column and 2) the presence (or not) of ionic strength. The bed depth-service time (BDST) model was applied to the sorption results to model the column operation. The removal efficiency of As(V) anions by the sorptive column was found to be higher than that of Cd cations. The presence of increased ionic strength caused a serious increase of removal efficiency for the case of arsenic anions. Granular akaganeite was less effective in all cases, but still, it remained a good adsorbent.
引用
收藏
页码:3967 / 3981
页数:15
相关论文
共 28 条
[1]   The removal of cadmium and lead from aqueous solution by ion exchange with Na-Y zeolite [J].
Ahmed, S ;
Chughtai, S ;
Keane, MA .
SEPARATION AND PURIFICATION TECHNOLOGY, 1998, 13 (01) :57-64
[2]   ARSENATE ADSORPTION ON AMORPHOUS ALUMINUM HYDROXIDE [J].
ANDERSON, MA ;
FERGUSON, JF ;
GAVIS, J .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1976, 54 (03) :391-399
[3]  
CHENG RC, 1994, J AM WATER WORKS ASS, V86, P79
[4]  
CHUNG YC, 1996, J CHEM TECHNOL BIOT, V69, P8
[5]   Sorption of As(V) ions by akaganeite-type nanocrystals [J].
Deliyanni, EA ;
Bakoyannakis, DN ;
Zouboulis, AI ;
Matis, KA .
CHEMOSPHERE, 2003, 50 (01) :155-163
[6]   Akaganeite-type β-FeO(OH) nanocrystals:: preparation and characterization [J].
Deliyanni, EA ;
Bakoyannakis, DN ;
Zouboulis, AI ;
Matis, KA ;
Nalbandian, L .
MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 42 (01) :49-57
[7]   Granular ferric hydroxide - a new adsorbent for the removal of arsenic from natural water [J].
Driehaus, W ;
Jekel, M ;
Hildebrandt, U .
JOURNAL OF WATER SERVICES RESEARCH AND TECHNOLOGY-AQUA, 1998, 47 (01) :30-35
[8]  
DRIEHAUS W, 1994, ENV SER, V133, P30
[9]  
EDWARDS M, 1989, J WATER POLLUT CON F, V61, P481
[10]  
*ENV RES SOFTW, 1994, MIN PLUS