Vibrational spectra and second harmonic generation in molecular complexes of L-lysine with L-tartaric, D,L-malic, acetic, arsenous, and fumaric acids

被引:52
作者
Marchewka, MK
Debrus, S
Ratajczak, H
机构
[1] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland
[2] Univ Paris 06, Lab Opt Solides, CNRS, UMR 7601, F-75252 Paris 05, France
[3] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
D O I
10.1021/cg030008v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Powder Kurtz-Perry measurements were performed for the title crystals. The efficiencies of second harmonic generation were determined (0.34, 0.84, 0.80, 0.97 and 1.01) relative to potassium hydrogen phosphate. The L-lysine moiety was characterized by wavenumbers and relative intensities of the infrared and Raman bands originating from internal vibrations. The presence of hydrogen bonds in the studied crystals is noted and the potential role of this type of intermolecular interaction in the second harmonic generation phenomena is discussed.
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页码:587 / 592
页数:6
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