Antihydrophobic cosolvent effects detect two different geometries for an S(N)2 displacement and the change to a single-electron-transfer mechanism in related cases

被引：14

作者：

Breslow, R

Connors, R

机构：

[1] Department of Chemistry, Columbia University, New York

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 26期

关键词：

D O I：

10.1021/ja960868i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：6323 / 6324

页数：2

共 12 条

[1] NONCHAIN PROCESSES IN NUCLEOPHILIC SUBSTITUTIONS TRIGGERED BY ELECTRON-TRANSFER (S(RN)1) - PHOTOCHEMICAL AND ELECTROCHEMICAL INDUCTION OF THE SUBSTITUTION OF 1-IODOADAMANTANE BY ARENETHIOLATE IONS [J].

AHBALA, M ;

HAPIOT, P ;

HOUMAM, A ;

JOUINI, M ;

PINSON, J ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (46) :11488-11498

[2] ROLE OF ENVIRONMENTAL-FACTORS IN THE DYNAMICS OF INTRAMOLECULAR DISSOCIATIVE ELECTRON-TRANSFER - EFFECT OF SOLVATION AND ION-PAIRING ON CLEAVAGE RATES OF ANION-RADICALS [J].

ANDRIEUX, CP ;

ROBERT, M ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (36) :9340-9346

[3] ELECTRON-TRANSFER AND BOND BREAKING - EXAMPLES OF PASSAGE FROM A SEQUENTIAL TO A CONCERTED MECHANISM IN THE ELECTROCHEMICAL REDUCTIVE CLEAVAGE OF ARYLMETHYL HALIDES [J].

ANDRIEUX, CP ;

LEGORANDE, A ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (17) :6892-6904

[4] QUANTITATIVE ANTIHYDROPHOBIC EFFECTS AS PROBES FOR TRANSITION-STATE STRUCTURES .2. DIELS-ALDER REACTIONS [J].

BRESLOW, R ;

ZHU, ZN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (39) :9923-9924

[5] QUANTITATIVE ANTIHYDROPHOBIC EFFECTS AS PROBES FOR TRANSITION-STATE STRUCTURES .1. BENZOIN CONDENSATION AND DISPLACEMENT-REACTIONS [J].

BRESLOW, R ;

CONNERS, RV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (24) :6601-6602

[6]

HUANG Y, 1993, J AM CHEM SOC, V115, P2157

[7] SUBSTITUTION-REACTIONS WHICH PROCEED VIA RADICAL-ANION INTERMEDIATES [J].

KORNBLUM, N .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (11) :734-745

[8] ON ELECTRON-TRANSFER IN ALIPHATIC NUCLEOPHILIC-SUBSTITUTION [J].

LUND, H ;

DAASBJERG, K ;

LUND, T ;

PEDERSEN, SU .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (07) :313-319

[9] THE SINGLE ELECTRON SHIFT AS A FUNDAMENTAL PROCESS IN ORGANIC-CHEMISTRY - THE RELATIONSHIP BETWEEN POLAR AND ELECTRON-TRANSFER PATHWAYS [J].

PROSS, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (07) :212-219

[10]

Saveant J.-M., 1990, Adv. Phys. Org. Chem., V26, P1

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