[pyH(+)](2)[CdNb2(py)(4)O2F10](2-)

被引：9

作者：

Halasyamani, P ^{[1
]}

Willis, MJ ^{[1
]}

Heier, KR ^{[1
]}

Stern, CL ^{[1
]}

Poeppelmeier, KR ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196007573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new Cd-II/Nb-V compound, bis(pyridinium) decafluoro-2 kappa(5)F,3 kappa 5F-di-mu-oxo-1:2 kappa(2)O;1:3 kappa(2)O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)(2) [CdNb2F10 O-2(C5H5N)(4)], has been synthesized. The complex contains [CdNb2(py)(4)F10O2](2-) anions (py is pyridine) linked via the pyridinium cation through N--H+... F hydrogen bonding. The anion is composed of two [NbF5O1/2](-) octahedra connected by O2- to a central [Cd(PY)(4)O-2/2] octahedron.

引用

页码：2491 / 2493

页数：3

共 12 条

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