Control of differential inclusion complexation in the solid state by seed crystals

被引：8

作者：

Yoshizawa, K ^{[1
]}

Toyota, S ^{[1
]}

Toda, F ^{[1
]}

Chatziefthimiou, S ^{[1
]}

Giastas, P ^{[1
]}

Mavridis, IM ^{[1
]}

Kato, M ^{[1
]}

机构：

[1] Okayama Univ Sci, Dept Chem, Okayama 7000005, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 32期

关键词：

crystal growth; host-guest systems; inclusion compounds; solid-state reactions;

D O I：

10.1002/anie.200501364

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Sowing the seeds: Complexation of rac-1 in the solid state with a guest such as Et2O in the gas phase proceeds in the presence of a seed crystal of the inclusion complex (see scheme). For example, passing Et2O over a mixture of 1 and a seed of 1·(Et2O)3 gives rise to exclusive formation of the 1:3 complex. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5097 / 5100

页数：4

共 16 条

[1] Temperature-controlled selectivity of isomeric guest inclusion:: enclathration and release of xylenes by 1,1′-binaphthyl-2,2′-dicarboxylic acid [J].