Direct determination of the spin-orbit reactivity in Cl(2P3/2,2P1/2)+H2/D2/HD reactions

被引：82

作者：

Dong, F ^{[1
]}

Lee, SH ^{[1
]}

Liu, K ^{[1
]}

机构：

[1] Acad Sinica, IAMS, Taipei 106, Taiwan

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 115卷 / 03期

关键词：

D O I：

10.1063/1.1378834

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By exploiting two different Cl-beam sources and concurrently monitoring the concentrations of the two reagents [Cl(P-2(3/2)) and Cl*(P-2(1/2))] and the H- or D-atom product, the spin-orbit specific excitation functions of the title reactions were determined. The exceptionally large nonadiabatic reactivity for Cl*(P-2(1/2))+n-H-2, inferred in our previous differential cross section investigation, is now confirmed and quantified. The isotope effects for both the spin-orbit ground and excited reagents are also elucidated. (C) 2001 American Institute of Physics.

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页码：1197 / 1204

页数：8

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