Comparison of coordination to RMg(+) and RZn(+) cations

被引：8

作者：

Tang, H ^{[1
]}

Richey, HG ^{[1
]}

机构：

[1] PENN STATE UNIV, DEPT CHEM, UNIVERSITY PK, PA 16802 USA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 23期

关键词：

D O I：

10.1021/om960648d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of a second coordinating agent (coord*) to a solution of RM(coord)(+) (M = Zn or Mg) leads to equilibrium mixtures of RM(coord)+ and RM-(coord*)(+). The equilibrium constants provide information about the relative abilities of different coordinating agents to coordinate to RM(+), The results for RMg(+) and RZn(+) are significantly different.

引用

页码：4891 / 4893

页数：3

共 25 条

[1]

ABEL EW, 1995, COMPREHENSIVE ORGANO, V3, pCH4

[2] HYDRATION OF ZINC IONS - A COMPARISON WITH MAGNESIUM AND BERYLLIUM IONS [J].

BOCK, CW ;

KATZ, AK ;

GLUSKER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (13) :3754-3763

[3]

BOERSMA J, 1982, COMPREHENSIVE ORGANO, pCH16

[4]

Christensen J.J., 1983, HDB METAL LIGAND HEA

[5] REACTIONS OF GRIGNARD-REAGENTS WITH AN AZACROWN ETHER - SYNTHESES OF RMG(14N4)+RMGX2- AND RMG(14N4)+X- [J].

FABICON, RM ;

PAJERSKI, AD ;

RICHEY, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) :9333-9334

[6] FORMATION OF ORGANOZINC CATIONS AND ANIONS FROM DIORGANOZINC COMPOUNDS [J].

FABICON, RM ;

PAJERSKI, AD ;

RICHEY, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) :6680-6681

[7] INTRAMOLECULAR COORDINATION IN ORGANOMETALLIC COMPOUNDS OF GROUP-2, GROUP-12, AND GROUP-13 [J].

GRUTER, GJM ;

VANKLINK, GPM ;

AKKERMAN, OS ;

BICKELHAUPT, F .

CHEMICAL REVIEWS, 1995, 95 (07) :2405-2456

[8] COVALENT VERSUS DATIVE BONDS TO MAIN GROUP-METALS, A USEFUL DISTINCTION [J].

HAALAND, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (08) :992-1007

[9] MAGNESIUM COMPOUNDS - CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA [J].

HOLLOWAY, CE ;

MELNIK, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 465 (1-2) :1-63

[10] THERMODYNAMIC AND KINETIC DATA FOR CATION MACROCYCLE INTERACTION [J].

IZATT, RM ;

BRADSHAW, JS ;

NIELSEN, SA ;

LAMB, JD ;

CHRISTENSEN, JJ .

CHEMICAL REVIEWS, 1985, 85 (04) :271-339

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