Solvent effect on hemin-catalyzed polymerization of phenols

被引：8

作者：

Akita, M ^{[1
]}

Tsutsumi, D ^{[1
]}

Kobayashi, M ^{[1
]}

Kise, H ^{[1
]}

机构：

[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan

来源：

BIOTECHNOLOGY LETTERS | 2001年 / 23卷 / 22期

关键词：

phenol; oxidative polymerization; hemin; solvent effect;

D O I：

10.1023/A:1012754624105

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Phenol and 4-substituted phenols were polymerized by H2O2 as an oxidant and hemin as a catalyst in organic/buffer mixed solvents. The chemical structures of the polymers were similar to those synthesized by the catalysis with horseradish peroxidase. Among the organic solvents used, pyridine gave the highest yield of polymer. Also, the manner of addition of H2O2 solution affected the polymer yield.

引用

页码：1827 / 1831

页数：5

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