Bridged phospholyl-amido titanium catalysts for ethylene polymerization

被引：57

作者：

Brown, SJ

Gao, XL

Harrison, DG

Koch, L

Spence, REV

Yap, GPA

机构：

[1] NOVA Res & Technol Corp, Calgary, AB T2E 7K7, Canada

[2] Univ Windsor, Dept Chem, Windsor, ON N9B 3P4, Canada

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 25期

关键词：

D O I：

10.1021/om9807710

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation, characterization, and an X-ray crystal structure for the first examples of covalently bridged phospholyl complexes of titanium are reported. Preliminary ethylene polymerization data for the ansa phospholyl-amido titanium complexes show catalyst activities comparable to the well-known bridged cyclopentadienyl-amido titanium constrained geometry catalysts.

引用

页码：5445 / 5447

页数：3

共 23 条

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