Soluble ferrocene conjugates for incorporation into self-assembled monolayers

被引：124

作者：

Yu, CJ ^{[1
]}

Chong, YC ^{[1
]}

Kayyem, JF ^{[1
]}

Gozin, M ^{[1
]}

机构：

[1] Clin Micro Sensors Inc, Pasadena, CA 91105 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1999年 / 64卷 / 06期

关键词：

D O I：

10.1021/jo982392m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of phenylethynyl oligomers (I-V) possessing a ferrocene and thiol at each termini have been synthesized. These oligomers have been designed to overcome the inherent insolubility of this class of complexes by substitution at the phenyl groups with methyl and propoxy substituents. Several new reactions for preparing arenethiol-protected compounds are described. Interestingly, the generation of an arenethiol anion during base- or fluoride-catalyzed deprotection has been characterized.

引用

页码：2070 / 2079

页数：10

共 41 条

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