Photochemical degradation of aqueous solutions of organic dyes under exposure to vacuum ultraviolet radiation

被引:11
作者
Zimina, GM
Zaitsev, NK
Krasnyi, DV
Karasev, AL
Vannikov, AV
机构
[1] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 117071, Russia
[2] NPP Ekoniks, Moscow 117071, Russia
关键词
D O I
10.1023/A:1026674507431
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A xenon excimer silent-discharge lamp of original design intended for use in photochemical processes is described. The wavelength of excited xenon excimers is 172 nm with a full width at half maximum of 16 nm. The operating efficiency of the lamp was demonstrated using the decolorization of aqueous solutions of the azo dye Acid Yellow 99 as an example. The photodegradation kinetics of the dye obeys an exponential law, as determined by measuring color decay at nu (max1) = 22000 cm(-1), and depends on the interaction of dye molecules with OH. radicals.
引用
收藏
页码:376 / 379
页数:4
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