Poly(2,5-dihydroxy-1,4-benzoquinone-3,6-methylene): a new organic polymer as positive electrode material for rechargeable lithium batteries

被引：181

作者：

Le Gall, T ^{[1
]}

Reiman, KH ^{[1
]}

Grossel, MC ^{[1
]}

Owen, JR ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF POWER SOURCES | 2003年 / 119卷

关键词：

positive electrode; rechargeable lithium battery; organic polymer; conducting polymer; ICP;

D O I：

10.1016/S0378-7753(03)00167-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new organic polymer as positive electrode material is presented. Poly(2,5-dihydroxy-1,4-benzoquinone-3,6-methylene) (PDBM) has oxocarbon cycles which are part of the polymer backbone and exhibit redox properties. Composite materials with acetylene black were investigated as positive electrodes for rechargeable lithium batteries. A specific capacity of 150 mAh g(-1) was reached with 40% acetylene black. The composite electrodes showed moderately good cyclability with less than 10% degradation in the first 100 cycles. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：316 / 320

页数：5