Synthesis and Characterization of 5-Octylthieno[3,4-c]pyrrole-4,6-dione Derivatives As New Monomers for Conjugated Copolymers

被引：63

作者：

Berrouard, Philippe ^{[1
]}

Grenier, Francois ^{[1
]}

Pouliot, Jean-Remi ^{[1
]}

Gagnon, Eric ^{[1
]}

Tessier, Christian ^{[1
]}

Leclerc, Mario ^{[1
]}

机构：

[1] Univ Laval, Dept Chim, Canada Res Chair Electroact & Photoact Polymers, Quebec City, PQ G1K 7P4, Canada

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SOLAR-CELLS;

D O I：

10.1021/ol1027514

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient route for the synthesis of 1-iodo-5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione as a key intermediate to build new electron-deficient monomers and related conjugated polymers is reported. Along these lines, two new low bandgap copolymers were synthesized from Stille or Suzuki coupling. These polymers were characterized and their properties compared to those of analogous conjugated polymers.

引用

页码：38 / 41

页数：4

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