Control of the Solid-State Chiral Optical Properties of a Supramolecular Organic Fluorophore Containing 4-(2-Arylethynyl)-Benzoic Acid

被引：48

作者：

Nishiguchi, Noriaki ^{[1
]}

Kinuta, Takafumi ^{[1
]}

Nakano, Yoko ^{[2
]}

Harada, Takunori ^{[3
]}

Tajima, Nobuo ^{[4
]}

Sato, Tomohiro ^{[1
]}

Fujiki, Michiya ^{[2
]}

Kuroda, Reiko ^{[3
]}

Matsubara, Yoshio ^{[1
]}

Imai, Yoshitane ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Osaka 5778502, Japan

[2] Nara Inst Sch & Technol, Grad Sch Mat Sci, Nara 6300192, Japan

[3] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

[4] Natl Inst Mat Sci, Computat Mat Sci Ctr, Tsukuba, Ibaraki 3050047, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 04期

关键词：

chirality; circular dichroism; circularly polarized luminescence; crystal-engineering; fluorescence; QUINOL-TYPE FLUOROPHORES; CORRELATED MOLECULAR CALCULATIONS; DIFFERENTIAL-OVERLAP TECHNIQUE; GAUSSIAN-BASIS SETS; INTERMEDIATE NEGLECT; HOST SYSTEM; PHOTOPHYSICAL PROPERTIES; FLUORESCENCE; EMISSION; (1R,2S)-2-AMINO-1,2-DIPHENYLETHANOL;

D O I：

10.1002/asia.201000780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solid-state chiral optical properties of a 4-(2-arylethynyl)-benzoic acid/amine supramolecular organic fluorophore can be controlled by changing the arylethynyl group of the achiral 4-(2-arylethynyl)-benzoic acid component molecule rather than the chirality of the amine component molecule.

引用

页码：1092 / 1098

页数：7

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