α-Scission of sulfonyl radicals:: a versatile process for organic synthesis

被引：62

作者：

Bertrand, F

Le Guyader, F

Liguori, L

Ouvry, G

Quiclet-Sire, B

Seguin, S

Zard, SZ ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

[2] Ecole Polytech, CNRS, Lab Synthese Organ, F-91128 Palaiseau, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 2001年 / 4卷 / 07期

关键词：

alkylsulfonyl radicals; trifluoromethanesulfonyl radicals; radical chains; allylation; vinylation; alkynylation; azidation;

D O I：

10.1016/S1387-1609(01)01270-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates. (C) 2001 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.

引用

页码：547 / 555

页数：9

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