Mixed cyclic trimers of porphyrins and dioxoporphyrins:: geometry vs. electronics in ligand recognition

被引：31

作者：

Clyde-Watson, Z ^{[1
]}

Bampos, N ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 11期

关键词：

D O I：

10.1039/a805504a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of metalloporphyrin-containing cyclic hosts has been prepared, which are electronically and geometrically programmed to recognize guests in a particular configuration. Electronic control is achieved by substituting the C-H meso positions with carbonyl groups, while geometric control is possible in the choice of the length of the rigid acetylene porphyrin linkers.

引用

页码：1135 / 1138

页数：4

共 14 条

[1] TEMPLATE-DIRECTED SYNTHESIS OF LINEAR AND CYCLIC BUTADIYNE-LINKED PORPHYRIN OLIGOMERS UP TO A LINEAR OCTAMER [J].

ANDERSON, S ;

ANDERSON, HL ;

SANDERS, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (18) :2247-2254

[2] MESO-OXIDATION OF SOME METALLOPORPHYRINS [J].

BARNETT, GH ;

EVANS, B ;

SMITH, KM .

TETRAHEDRON, 1975, 31 (21) :2711-2717

[3] PROTON MAGNETIC RESONANCE STUDIES OF PORPHYRINS [J].

BECKER, ED ;

BRADLEY, RB ;

WATSON, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (18) :3743-&

[4]

BIEDERMANN HG, 1974, Z NATURFORSCH B, VB 29, P360

[5] Reversing the stereochemistry of a Diels-Alder reaction: use of metalloporphyrin oligomers to control transition state stability [J].

Clyde-Watson, Z ;

Vidal-Ferran, A ;

Twyman, LJ ;

Walter, CJ ;

McCallien, DWJ ;

Fanni, S ;

Bampos, N ;

Wylie, RS ;

Sanders, JKM .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (05) :493-502

[6] DABCO METALLOPORPHYRIN BINDING - TERNARY COMPLEXES, HOST GUEST CHEMISTRY, AND THE MEASUREMENT OF PI-PI-INTERACTIONS [J].

HUNTER, CA ;

MEAH, MN ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (15) :5773-5780

[7] COPPER(I) CHLORIDE [J].

KELLER, RN ;

WYCOFF, HD .

INORGANIC SYNTHESES, 1946, 2 :1-4

[8] SYNTHESIS USING PYRIDINIUM SALTS .5. SPECIFIC SYNTHESIS OF PYRIDINES AND OLIGOPYRIDINES [J].

KROHNKE, F .

SYNTHESIS-STUTTGART, 1976, (01) :1-24

[9] Acceleration of a hetero-Diels-Alder reaction by cyclic metalloporphyrin trimers [J].

Marty, M ;

Clyde-Watson, Z ;

Twyman, LJ ;

Nakash, M ;

Sanders, JKM .

CHEMICAL COMMUNICATIONS, 1998, (20) :2265-2266

[10] Stereospecific templated synthesis of a triruthenium butadiyne-linked cyclic porphyrin trimer [J].

Marvaud, V ;

VidalFerran, A ;

Webb, SJ ;

Sanders, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (06) :985-990

← 1 2 →