Control over directional metal-metal charge transfer in cyanide-bridged dimanganese complexes:: effects of μ-CN linkage isomerism and ancillary ligand set

被引：12

作者：

Anderson, KM ^{[1
]}

Connelly, NG ^{[1
]}

Llamas-Rey, E ^{[1
]}

Orpen, AG ^{[1
]}

Paul, RL ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b104998b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis and characterisation of cyano-bridged complexes of the form [(eta -C5R4Me)L(ON)Mn(mu -XY)Mn(CO)(2)-L'(dppm)](Z) (X,Y = C,N; z = 1-3) shows that systematic variation of the orientation of the CN bridge and the nature and geometric arrangement of the ancillary ligands affords control of the direction and energy of metal-metal charge transfer in the mixed valence dications.

引用

页码：1734 / 1735

页数：2

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