Design of an 80 kWe PEM fuel cell system:: Scale up effect investigation

被引:33
作者
Bonnet, C. [1 ]
Didierjean, S. [2 ]
Guillet, N. [3 ]
Besse, S. [4 ]
Colinart, T. [2 ]
Carre, P. [1 ]
机构
[1] Univ Nancy 2, CNRS, Lab Sci Genie Chim, F-54001 Nancy, France
[2] Nancy Univ, CNRS, Lab Energet & Mecan Theor & Appl, F-54504 Vandoeuvre Les Nancy, France
[3] CEA, LITEN DTH LCPEM, F-38054 Grenoble 9, France
[4] Helion, F-13545 Aix En Provence 4, France
关键词
PEM fuel cell; scaling effect; durability; water management; impedance spectroscopy;
D O I
10.1016/j.jpowsour.2007.12.100
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the frame of SPACT-80 project to design and manufacture a robust and durable air/hydrogen 80 kWe PEM fuel cell for transportation application, experiments have been carried out on various electrode active surfaces since the full scale system could be damaged by some particular operating conditions. Thus, the main objective of this paper was to verify that a 25 cm 2 single cell, a 5-cell pilot stack and a 90-cell stack exhibit the same behaviour and that they are representative of the full device's performance. After a brief description of the studied device the scaling up effect was checked. In non-optimal conditions, experiments were mainly conducted on single cell and pilot stack. In driving cycle and when studying various gas flows, they present similar evolution for the cell voltage as well as for the water management. The water transport coefficient and the diffusion resistance values determined by impedance spectroscopy highlight the presence of liquid water that could have an effect on the gas transport to the electrode. Investigation on the air humidification conditions shows that at lower relative humidity (RH), the two fuel cells have similar behaviour but above 60% RH different evolutions appear. Whatever the air humidification conditions, liquid water is present in both compartments. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:441 / 448
页数:8
相关论文
共 15 条
[1]   Electrocatalysts for fuel cells [J].
Acres, GJK ;
Frost, JC ;
Hards, GA ;
Potter, RJ ;
Ralph, TR ;
Thompsett, D ;
Burstein, GT ;
Hutchings, GJ .
CATALYSIS TODAY, 1997, 38 (04) :393-400
[2]   Effect of gas dilution on PEM fuel cell performance and impedance response [J].
Boillot, M ;
Bonnet, C ;
Jatroudakis, N ;
Carre, P ;
Didierjean, S ;
Lapicque, F .
FUEL CELLS, 2006, 6 (01) :31-37
[3]   Operating proton exchange membrane fuel cells without external humidification of the reactant gases - Fundamental aspects [J].
Buchi, FN ;
Srinivasan, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (08) :2767-2772
[4]   Effect of water transport properties on a PEM fuel cell operating with dry hydrogen [J].
Cai, Yinghua ;
Hu, Jun ;
Ma, Haipeng ;
Yi, Baolian ;
Zhang, Huamin .
ELECTROCHIMICA ACTA, 2006, 51 (28) :6361-6366
[5]   Characterisation and modelling of a 5 kW PEMFC for transportation applications [J].
Candusso, D ;
Harel, F ;
De Bernardinis, A ;
François, X ;
Péra, MC ;
Hissel, D ;
Schott, P ;
Coquery, G ;
Kauffmann, JM .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (08) :1019-1030
[6]   Comparative studies of polymer electrolyte membrane fuel cell stack and single cell [J].
Chu, D ;
Jiang, RZ .
JOURNAL OF POWER SOURCES, 1999, 80 (1-2) :226-234
[7]   Effect of membrane characteristics and humidification conditions on the impedance response of polymer electrolyte fuel cells [J].
Freire, TJP ;
Gonzalez, ER .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 503 (1-2) :57-68
[8]  
Gottesfeld S, 1997, ADV ELECTROCHEM SCI, V5, P195, DOI DOI 10.1002/9783527616794.CH4
[9]  
GUILLET N, 2007, INT EL VEH S EXP AN
[10]   Modelistic interpretation of the impedance response of a polymer electrolyte fuel cell [J].
Paganin, VA ;
Oliveira, CLF ;
Ticianelli, EA ;
Springer, TE ;
Gonzalez, ER .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3761-3766