Studies on an ionic liquid based on FeCl3 and its properties

被引:101
作者
Zhang, QG
Yang, JZ [1 ]
Lu, XM
Gui, JS
Huang, Z
机构
[1] Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
[2] Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
[3] Shenyang Normal Univ, Dept Chem, Shenyang 110032, Peoples R China
基金
中国国家自然科学基金;
关键词
ionic liquid; density; surface tension; FeCl3; BMIC; interstice theory;
D O I
10.1016/j.fluid.2004.09.020
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper reports that an ionic liquid has been prepared by directly mixing FeCl3 and 1-methyl-3-butylimidazolium chloride (BMIC) with molar ratio 1/1 under dry argon atmosphere. We determined the densities, and surface tension of the pure ionic liquid (IL) in temperature range from 283.15 to 343.15 +/- 0.1 K. The volumetric properties and the properties of surface for ionic liquid were discussed. The interstice theory is put forward and the thermal expansion coefficient. a, calculated using the new theory is in good agreement with experimental value. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:207 / 211
页数:5
相关论文
共 25 条
[1]  
Adamson AW, 1986, PHYS CHEM SURFACES
[2]  
[Anonymous], 2002, ACS S SER
[3]  
BOCKRIS JO, 1970, MODERN ELECTROCHEMIS, P533
[4]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[5]  
Endres F, 2002, CHEMPHYSCHEM, V3, P144, DOI 10.1002/1439-7641(20020215)3:2<144::AID-CPHC144>3.0.CO
[6]  
2-#
[7]   Lattice and phase transition thermodynamics of ionic liquids [J].
Glasser, L .
THERMOCHIMICA ACTA, 2004, 421 (1-2) :87-93
[8]   Standard absolute entropies, SO298, from volume or density -: Part II.: Organic liquids and solids [J].
Glasser, L ;
Jenkins, HDB .
THERMOCHIMICA ACTA, 2004, 414 (02) :125-130
[9]   LATTICE ENERGIES OF CRYSTALS WITH MULTIPLE IONS - A GENERALIZED KAPUSTINSKII EQUATION [J].
GLASSER, L .
INORGANIC CHEMISTRY, 1995, 34 (20) :4935-4936
[10]  
Huang Z.Q., 1983, INTRO ELECTROLYTE SO, P98