Chemical stability of lithiated-HOPG with some organic electrolytes

被引：12

作者：

Yazami, R ^{[1
]}

Geniès, S ^{[1
]}

机构：

[1] Inst Natl Polytech Grenoble, UMR 5631 CNRS, Lab Electrochim & Physicochim Mat & Interfaces, F-38402 St Martin Dheres, France

来源：

DENKI KAGAKU | 1998年 / 66卷 / 12期

关键词：

graphite-lithium; stability; organic electrolytes; ternary GICs;

D O I：

10.5796/kogyobutsurikagaku.66.1293

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Stage-1 LiC6 was prepared from HOPG samples and reacted with several electrolytes of 1 moldm(-3) solution of LiPF6 in a single or binary organic solvent(s). The changes in the external aspects of the samples were described by photography and those in the crystal structure were analyzed by X-ray diffraction. Ternary CnLi(solv.)(y) were formed with all single solvent electrolytes except with ethylene carbonate (EC). The presence of EC in binary electrolytes is shown to significantly reduce the co-intercalation of organic molecules and thus enhance the electrolyte stability.

引用

页码：1293 / 1298

页数：6

共 12 条

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