Desolvation of ions in subnanometer pores and its effect on capacitance and double-layer theory

被引：578

作者：

Chmiola, John ^{[1
]}

Largeot, Celine ^{[2
]}

Taberna, Pierre-Louis ^{[2
]}

Simon, Patrice ^{[2
]}

Gogotsi, Yury ^{[1
]}

机构：

[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA

[2] Univ Toulouse 3, CNRS, UMR 5085, CIRIMAT, F-31062 Toulouse 4, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 18期

关键词：

electrochemistry; ion pairs; nanostructures; porosity; solvation;

D O I：

10.1002/anie.200704894

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recasting the double layer: The implicit assumption that electrochemical double layers are governed only by ion/electrode charge separation may be short-sighted and lead to a fundamental misunderstanding of the phenomenological response. This is shown in a study performed on ions confined in nanoporous carbon with pores smaller than the size of an ion surrounded by a solvation shell (see picture; TEA+=tetraethylammonium, AN=acetonitrile). (Chemical Equation). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3392 / 3395

页数：4

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