An analysis of condensation nuclei levels at Mace Head, Ireland

Condensation nuclei (CN) concentrations measured at Mace Head between 1990 and 1992 are presented. The background CN concentration was found to typically range from 100 to 700 cm(-3). Concentration values were in this range for 55% of the measurement period. No seasonal cycle was observed in the CN concentration values. Concurrent equivalent black carbon (EBC) measurements are used to examine anthropogenic influences on the background CN concentration. Evidence that transatlantic air mass transport influenced the background CN concentration, contributing to increased CN and EBC levels, is shown. During polluted conditions the CN concentration was generally higher than 1000 cm(-3). The principal source for high pollution levels was European air masses arriving at the site. Very high CN concentrations, greater than 50 000 cm(-3), are attributed to local gas-to-particle conversion processes. The characteristics of a number of particle production events are considered. These show that these events are highly photochemical and occur during both clean and polluted conditions. Such production events though infrequent contributed significantly to the total aerosol number concentration. (C) 1999 Elsevier Science Ltd. All rights reserved.