Some problems concerning the evaluation of non-isothermal kinetic parameters - Solid-gas decompositions from thermogravimetric

被引：69

作者：

Budrugeac, P

Petre, AL

Segal, E

机构：

[1] EUROTEST SA,BUCHAREST 73204,ROMANIA

[2] ROMANIAN ACAD,IG MURGULESCU INST PHYS CHEM,BUCHAREST 77208,ROMANIA

[3] UNIV BUCHAREST,FAC CHEM,DEPT PHYS CHEM,BUCHAREST,ROMANIA

来源：

JOURNAL OF THERMAL ANALYSIS | 1996年 / 47卷 / 01期

关键词：

non-isothermal kinetics; thermogravimetry;

D O I：

10.1007/BF01982692

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The validity of isoconversional methods used to evaluate the activation energy is discussed. The authors have shown that the Flynn-Wall-Ozawa and Friedman methods give results that agree with each other only if the activation energy does not change with the degree of conversion. A criterion for the reaction mechanism as expressed by the differential conversion function is suggested too.

引用

页码：123 / 134

页数：12

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[Anonymous], J POLYM SCI

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THE COMPENSATION EFFECT IN THE NONISOTHERMAL DEGRADATION OF POLYCHLOROPRENE RUBBER [J].