Hollow mesoporous silica fibers:: tubules by coils of tubules

被引:56
作者
Kleitz, F [1 ]
Wilczok, U [1 ]
Schüth, F [1 ]
Marlow, F [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1039/b105083b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hollow mesoporous silica fibers have been synthesized under acidic conditions in a two-phase static system. The fibers always have a circular internal architecture with hexagonally arranged channels running perpendicularly around the fiber axis. The inner radius of the hollow fibers is variable and the fibers are connected with solid fibers without inner cavity. This points to a novel formation mechanism for the central cavity of the hollow fibers.
引用
收藏
页码:3486 / 3489
页数:4
相关论文
共 29 条
[1]   Mesoporous silica synthesized by solvent evaporation: Spun fibers and spray-dried hollow spheres [J].
Bruinsma, PJ ;
Kim, AY ;
Liu, J ;
Baskaran, S .
CHEMISTRY OF MATERIALS, 1997, 9 (11) :2507-2512
[2]   Platinum-filled oxidic nanotubes [J].
Hippe, C ;
Wark, M ;
Lork, E ;
Schulz-Ekloff, G .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 31 (03) :235-239
[3]   Formation of a titanium dioxide nanotube array [J].
Hoyer, P .
LANGMUIR, 1996, 12 (06) :1411-1413
[4]   Room temperature growth of mesoporous silica fibers: A new high-surface-area optical waveguide [J].
Huo, QS ;
Zhao, DY ;
Feng, JL ;
Weston, K ;
Buratto, SK ;
Stucky, GD ;
Schacht, S ;
Schuth, F .
ADVANCED MATERIALS, 1997, 9 (12) :974-&
[5]  
Kasuga T, 1999, ADV MATER, V11, P1307, DOI 10.1002/(SICI)1521-4095(199910)11:15<1307::AID-ADMA1307>3.0.CO
[6]  
2-H
[7]  
KLEITZ F, UNPUB CHEM MAT
[8]   Preparation of TiO2 hollow-fibers using supramolecular assemblies [J].
Kobayashi, S ;
Hanabusa, K ;
Hamasaki, N ;
Kimura, M ;
Shirai, H ;
Shinkai, S .
CHEMISTRY OF MATERIALS, 2000, 12 (06) :1523-+
[9]   Mesoporous molecular sieves MCM-41 with a hollow tubular morphology [J].
Lin, HP ;
Cheng, S ;
Mou, CY .
CHEMISTRY OF MATERIALS, 1998, 10 (02) :581-589
[10]   ''Tubules-within-a-tubule'' hierarchical order of mesoporous molecular sieves in MCM-41 [J].
Lin, HP ;
Mou, CY .
SCIENCE, 1996, 273 (5276) :765-768