Reversible α-elimination in the conversion of N-CH3 to N-CH=Ir by double C-H activation

被引：72

作者：

Lee, DH ^{[1
]}

Chen, JY

Faller, JW

Crabtree, RH

机构：

[1] Chonbuk Natl Univ, Dept Chem, Chonju 561756, South Korea

[2] Yale Univ, Chem Lab, New Haven, CT 06520 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 02期

关键词：

D O I：

10.1039/b007679l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Dimethylaminopyridine (pyNMe(2); py = 2-pyridyl) reacts with [H2Ir(OCMe2)(2)L-2](+) (L = PPh3) to give a cyclic carbene complex [H2Ir(=CHN(Me)py)L-2](+) via an oxidative addition, reversible alpha -elimination sequence.

引用

页码：213 / 214

页数：2

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