Ionothermal synthesis of unusual choline-templated cobalt aluminophosphates

被引：119

作者：

Drylie, Ewan A.

Wragg, David S.

Parnham, Emily R.

Wheatley, Paul S.

Slawin, Alexandra M. Z.

Warren, John E.

Morris, Russell E. ^{[1
]}

机构：

[1] Univ St Andrews, EaStChem Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] CCLRC, Daresbury Lab, Synchrotron Radiat Source, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

eutectic mixtures; ionic liquids; ionothermal synthesis; synthetic methods; zeolite analogues;

D O I：

10.1002/anie.200702239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Into the deep: A deep-eutectic solvent based on choline chloride and one of several carboxylic acids can be used to prepare cobalt aluminophosphate analogues of zeolites. One of the new materials contains unusual ring-opened double-four-ring units, in which a cobalt atom forms a terminal Co-Cl bond (see picture; Co cyan, Al gray, P purple, O red, Cl green). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7839 / 7843

页数：5

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