Chemical vapor deposition of ruthenium dioxide thin films from bis(2,4-dimethylpentadienyl)ruthenium

被引:10
作者
Meda, L [1 ]
Breitkopf, RC [1 ]
Haas, TE [1 ]
Kirss, RU [1 ]
机构
[1] Northeastern Univ, Dept Chem, Boston, MA 02115 USA
来源
CHEMICAL ASPECTS OF ELECTRONIC CERAMICS PROCESSING | 1998年 / 495卷
关键词
D O I
10.1557/PROC-495-75
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Thin films of polycrystalline RuO2 were deposited from bis(2, 4-dimethylpentadienyl) ruthenium, (eta(5)-2, 4-Me2C5H5)(2)Ru (1) and ruthenocene (2) on quartz and silicon substrates between 200 and 500 degrees C under Ar/O-2 or O-2. Films deposited from 1 were more adherent than those grown from 2 under the same conditions, however, none of the films were particularly adherent when O-2 was used as a carrier gas. SEM revealed a columnar structure for both precursors with grain size ranging from 0.15 - 1 5 mu. Crystallinity increased after annealing the films to 800 degrees C. Resistivity decreased as the annealing temperature increased.
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页码:75 / 80
页数:6
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