Ligand-mediated addition of organometallic reagents to azomethine functions

被引：142

作者：

Denmark, SE

Nicaise, OJC

机构：

[1] Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana

[2] Univ. Catholique de Louvain, Lab. de Chim. Organique de Synt., B-1348 Louvain-La-Neuve, Place Louis Pasteur

[3] University of Illinois, Urbana-Champaign, IL

[4] Univ. Catholique de Louvain, Lab. de Chim. Organique de Synt., Louvain-la-Neuve

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 09期

关键词：

D O I：

10.1039/cc9960000999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Despite the enormous progress made in the asymmetric addition of nucleophiles to prochiral carbonyl compounds for the preparation of chiral alcohols, the corresponding study of enantioselective conversion of prochiral azomethine functions to chiral amines remains a relatively undeveloped area of research, This account reviews the current state of this new field of investigation.

引用

页码：999 / 1004

页数：6

共 76 条

[1] [Anonymous], ANGEW CHEM
[2] Ariens E.J., 1983, STEREOCHEMISTRY BIOL
[3] COMPLEX-INDUCED PROXIMITY EFFECTS - ENANTIOSELECTIVE SYNTHESES BASED ON ASYMMETRIC DEPROTONATIONS OF N-BOC-PYRROLIDINES
BEAK, P
KERRICK, ST
WU, SD
CHU, JX
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) : 3231 - 3239
[4] ASYMMETRIC SUBSTITUTION - HIGHLY ENANTIOSELECTIVE SUBSTITUTIONS INDUCED AT THE CARBANION OF A RACEMIC ORGANOLITHIUM SUBSTRATE BY (-)-SPARTEINE
BEAK, P
DU, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (06) : 2516 - 2518
[5] THE CHIRAL POOL AS A SOURCE OF ENANTIOSELECTIVE CATALYSTS AND AUXILIARIES
BLASER, HU
[J]. CHEMICAL REVIEWS, 1992, 92 (05) : 935 - 952
[6] BIS(4,5-DIHYDROOXAZOLYL) DERIVATIVES IN ASYMMETRIC CATALYSIS
BOLM, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05): : 542 - 543
[7] Bolm C., 1991, ANGEW CHEM, V103, P556
[8] CATALYTIC ASYMMETRIC REDUCTIVE AMINATION OF KETONES VIA HIGHLY ENANTIOSELECTIVE HYDROGENATION OF THE C=N DOUBLE-BOND
BURK, MJ
MARTINEZ, JP
FEASTER, JE
COSFORD, N
[J]. TETRAHEDRON, 1994, 50 (15) : 4399 - 4428
[9] Collins A.N., 1992, CHIRALITY IND COMMER
[10] Denmark S. E., UNPUB

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