Structure and Electrochemistry of Thin-Film Oxides Grown by Laser-Pulsed Deposition

被引：30

作者：

Julien, C. ^{[1
]}

Haro-Poniatowski, E. ^{[2
]}

Hussain, O. M. ^{[3
]}

Ramana, C. V. ^{[3
]}

机构：

[1] Univ Paris 06, UMR 7603, LMDH, F-75252 Paris 05, France

[2] Univ Autonoma Metropolitana Iztapalapa, Lab Opt Cuant, Mexico City 09340, DF, Mexico

[3] Sri Venkateswara Univ, Thin Film Lab, Dept Phys, Tirupati 517502, Andhra Pradesh, India

来源：

IONICS | 2001年 / 7卷 / 03期

关键词：

Specific Capacity; Raman Scattering Spectrum; Laser Ablation Technique; High Voltage Region; Raman Scattering Spectroscopy;

D O I：

10.1007/BF02419223

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thin films of V(2)O(5), LiCoO(2) and LiMn(2)O(4) were grown by pulsed-laser deposition in the view of their use in lithium microbatteries. Lithiated polycrystalline crystalline thin dense films grown without post-deposition annealing were formed onto substrates maintained at low temperature (300 degrees C) from a sintered composite target including Li(2)O as additive. The structural characterizations of these films have been carried out by X-ray diffraction and Raman scattering spectroscopy. The electrochemical features of thin films are investigated by cyclic voltammetry and their charge-discharge profiles in lithium microbatteries are shown.

引用

收藏

页码：165 / 171

页数：7

相关论文

共 15 条

[1] THIN-FILM LI-LIMN2O4 BATTERIES [J].

BATES, JB ;

LUBBEN, D ;

DUDNEY, NJ .

IEEE AEROSPACE AND ELECTRONIC SYSTEMS MAGAZINE, 1995, 10 (04) :30-32

[2] LiMn2O4 Films Grown by Pulsed-Laser Deposition [J].

Camacho-Lopez, M. A. ;

Escobar-Alarcon, L. ;

Haro-Poniatowski, E. ;

Julien, C. .

IONICS, 1999, 5 (3-4) :244-250

[3] THE LIXV2O5 SYSTEM - AN OVERVIEW OF THE STRUCTURE MODIFICATIONS INDUCED BY THE LITHIUM INTERCALATION [J].

DELMAS, C ;

COGNACAURADOU, H ;

COCCIANTELLI, JM ;

MENETRIER, M ;

DOUMERC, JP .

SOLID STATE IONICS, 1994, 69 (3-4) :257-264

[4] LiCoO2 thin films grown by pulsed laser deposition on low cost substrates [J].

Ginley, DS ;

Perkins, JD ;

McGraw, JM ;

Parilla, PA ;

Fu, ML ;

Rogers, CT .

MATERIALS FOR ELECTROCHEMICAL ENERGY STORAGE AND CONVERSION II-BATTERIES, CAPACITORS AND FUEL CELLS, 1998, 496 :293-302

[5] Growth of LiMn2O4 thin films by pulsed-laser deposition and their electrochemical properties in lithium microbatteries [J].

Julien, C ;

Haro-Poniatowski, E ;

Camacho-Lopez, MA ;

Escobar-Alarcon, L ;

Jimenez-Jarquin, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 72 (01) :36-46

[6] 4-Volt Cathode Materials for Rechargeable Lithium Batteries Wet-Chemistry Synthesis, Structure and Electrochemistry [J].

Julien, C. .

IONICS, 2000, 6 (1-2) :30-46

[7] Growth of V2O5 thin films by pulsed laser deposition and their applications in lithium microbatteries [J].

Julien, C ;

Haro-Poniatowski, E ;

Camacho-López, MA ;

Escobar-Alarcón, L ;

Jímenez-Jarquín, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1999, 65 (03) :170-176

[8]

JULIEN C, 1993, LITHIUM BATTERIES NE, P167

[9]

JULIEN C, 2000, MATER CHEM PHYS, V67, P1

[10] LiMn2O4 thin films for lithium ion sensors [J].

Morcrette, M ;

Barboux, P ;

Perriere, J ;

Brousse, T .

SOLID STATE IONICS, 1998, 112 (3-4) :249-254