Interactive n->sigma delocalizations that control an aqueous organic equilibrium

被引：1

作者：

Fan, YH ^{[1
]}

Haseltine, J ^{[1
]}

机构：

[1] GEORGIA INST TECHNOL,SCH CHEM & BIOCHEM,ATLANTA,GA 30332

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(97)82941-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrated acetaldehydes were condensed in D2O with substituted alcohols and thiols to determine Delta G Of hemiacetalization by H-1 NMR. Specific n-->sigma* delocalizations in the alkoxy/alkylthio functionality of the product interact to influence n-->sigma* delocalization in the hemiacetal functionality. Delocalization in the latter functionality controls Delta G. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：9279 / 9282

页数：4

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