Review on gel polymer electrolytes for lithium batteries

被引:1195
作者
Stephan, AM [1 ]
机构
[1] Cent Electrochem Res Inst, Electrochem Power Syst Div, Karaikkudi 630006, Tamil Nadu, India
关键词
polymer electrolytes; ionic conductivity; plasticizers; compatibility; phase inversion technique;
D O I
10.1016/j.eurpolymj.2005.09.017
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper reviews the state-of-art of polymer electrolytes in view of their electrochemical and physical properties for the applications in lithium batteries. This review mainly encompasses on five polymer hosts namely poly(ethylene oxide) (PEO), poly(acrylonitrile) (PAN), poly(methyl methacrylate) (PMMA), poly(vinylidene fluoride) (PVdF) and poly(vinylidene fluoride-hexafluoro propylene) (PVdF-HFP) as electrolytes. Also the ionic conductivity, morphology, porosity and cycling behavior of PVdF-HFP membranes prepared by phase inversion technique with different non-solvents have been presented. The cycling behavior of LiMn2O4/polymer electrolyte (PE)/Li cells is also described. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:21 / 42
页数:22
相关论文
共 157 条
[1]   AMBIENT-TEMPERATURE RECHARGEABLE POLYMER-ELECTROLYTE BATTERIES [J].
ABRAHAM, KM ;
ALAMGIR, M .
JOURNAL OF POWER SOURCES, 1993, 43 (1-3) :195-208
[2]   LI+-CONDUCTIVE SOLID POLYMER ELECTROLYTES WITH LIQUID-LIKE CONDUCTIVITY [J].
ABRAHAM, KM ;
ALAMGIR, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (05) :1657-1657
[3]   A novel fire-retardant polyacrylonitrile-based gel electrolyte for lithium batteries [J].
Akashi, H ;
Sekai, K ;
Tanaka, K .
ELECTROCHIMICA ACTA, 1998, 43 (10-11) :1193-1197
[4]   LI ION CONDUCTIVE ELECTROLYTES BASED ON POLY(VINYL CHLORIDE) [J].
ALAMGIR, M ;
ABRAHAM, KM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :L96-L97
[5]   Electrochemical investigation of lithium aromatic sulfonyl imide salts [J].
Alloin, F ;
Bayoud, S ;
Azimipour, B ;
Reibel, L ;
Sanchez, JY .
ELECTROCHIMICA ACTA, 2000, 45 (8-9) :1193-1201
[6]   Hot-pressed, solvent-free, nanocomposite, PEO-based electrolyte membranes II.: All solid-state Li/LiFePO4 polymer batteries [J].
Appetecchi, GB ;
Hassoun, J ;
Scrosati, B ;
Croce, F ;
Cassel, F ;
Salomon, M .
JOURNAL OF POWER SOURCES, 2003, 124 (01) :246-253
[7]   KINETICS AND STABILITY OF THE LITHIUM ELECTRODE IN POLY(METHYLMETHACRYLATE)-BASED GEL ELECTROLYTES [J].
APPETECCHI, GB ;
CROCE, F ;
SCROSATI, B .
ELECTROCHIMICA ACTA, 1995, 40 (08) :991-997
[8]   PEO-LiN(SO2CF2CF3)2 polymer electrolytes -: I.: XRD, DSC, and ionic conductivity characterization [J].
Appetecchi, GB ;
Henderson, W ;
Villano, P ;
Berrettoni, M ;
Passerini, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (10) :A1171-A1178
[9]   A lithium ion polymer battery [J].
Appetecchi, GB ;
Scrosati, B .
ELECTROCHIMICA ACTA, 1998, 43 (09) :1105-1107
[10]   High-performance gel-type lithium electrolyte membranes [J].
Appetecchi, GB ;
Croce, F ;
Romagnoli, P ;
Scrosati, B ;
Heider, U ;
Oesten, R .
ELECTROCHEMISTRY COMMUNICATIONS, 1999, 1 (02) :83-86