Synthesis of 1,10-N,N'-phenanthroline dioxides using HOF•CH3CN complex

被引：21

作者：

Carmeli, M ^{[1
]}

Rozen, S ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 06期

关键词：

D O I：

10.1021/jo047960e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] HOF-CH3CN, a very efficient oxygen-transfer agent, made readily from F-2, H2O, and CH3CN, was reacted with various 1,10-phenanthroline derivatives to form the corresponding N,N'-dioxides in good yields and short reaction times.

引用

页码：2131 / 2134

页数：4

共 26 条

[1]

Antkowiak R, 1998, HETEROCYCLES, V47, P893

[2] TRANSFORMATIONS IN 1,10-PHENANTHROLINE SERIES [J].

COREY, EJ ;

BORROR, AL ;

FOGLIA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (01) :288-&

[3] Cluster chemical ionization and deuterium exchange mass spectrometry in supersonic molecular beams [J].

Dagan, S ;

Amirav, A .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1996, 7 (06) :550-558

[4]

Dayan S, 1999, SYNTHESIS-STUTTGART, P1427

[5] Cluster chemical ionization for improved confidence level in sample identification by gas chromatography/mass spectrometry [J].

Fialkov, AB ;

Amirav, A .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2003, 17 (12) :1326-1338

[6] NONEXISTENCE OF 1,10-PHENANTHROLINE-N,N'-DIOXIDE [J].

GILLARD, RD .

INORGANICA CHIMICA ACTA-LETTERS, 1981, 53 (04) :L173-L173

[7] Easy way for constructing hard-to-make epoxides employing HOF•CH3CN [J].

Golan, E ;

Hagooly, A ;

Rozen, S .

TETRAHEDRON LETTERS, 2004, 45 (17) :3397-3399

[8] A fast, high-yield preparation of vicinal dinitro compounds using HOF•CH3CN [J].

Golan, E ;

Rozen, S .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (23) :9170-9172

[9]

Katz TJ, 2000, ANGEW CHEM INT EDIT, V39, P1921, DOI 10.1002/1521-3773(20000602)39:11<1921::AID-ANIE1921>3.0.CO

[10]

2-F

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