Density fluctuations and the structure of a nonuniform hard sphere fluid

被引:14
作者
Katsov, K [1 ]
Weeks, JD
机构
[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
[2] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.86.440
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We derive an exact equation for density changes induced by a general external field that corrects the hydrostatic approximation where the local value of the field is adsorbed into a modified chemical potential. Using linear response theory to relate density changes self-consistently in different regions of space, we arrive at an integral equation for a hard sphere fluid that is exact in the limit of a slowly varying field or at low density and reduces to the accurate Percus-Yevick equation for a hard core field. This and related equations give accurate results for a wide variety of fields.
引用
收藏
页码:440 / 443
页数:4
相关论文
共 17 条
[1]   GAUSSIAN FIELD MODEL OF FLUIDS WITH AN APPLICATION TO POLYMERIC FLUIDS [J].
CHANDLER, D .
PHYSICAL REVIEW E, 1993, 48 (04) :2898-2905
[2]   Gaussian statistics of the hard-sphere fluid [J].
Crooks, GE ;
Chandler, D .
PHYSICAL REVIEW E, 1997, 56 (04) :4217-4221
[3]  
HANSEN J. P., 2013, Theory of Simple Liquids
[4]   Cavity formation and the drying transition in the Lennard-Jones fluid [J].
Huang, DM ;
Chandler, D .
PHYSICAL REVIEW E, 2000, 61 (02) :1501-1506
[5]   An information theory model of hydrophobic interactions [J].
Hummer, G ;
Garde, S ;
Garcia, AE ;
Pohorille, A ;
Pratt, LR .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1996, 93 (17) :8951-8955
[6]  
KATSOV K, IN PRESS
[7]  
KATSOV K, THESIS U MARYLAND
[8]   Hydrophobicity at small and large length scales [J].
Lum, K ;
Chandler, D ;
Weeks, JD .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (22) :4570-4577
[9]  
Percus J. K., 1964, EQUILIBRIUM THEORY C, P33
[10]   APPROXIMATION METHODS IN CLASSICAL STATISTICAL MECHANICS [J].
PERCUS, JK .
PHYSICAL REVIEW LETTERS, 1962, 8 (11) :462-&