NMR of supercritical laser-polarized xenon

被引:27
作者
Haake, M
Goodson, BM
Laws, DD
Brunner, E
Cyrier, MC
Havlin, RH
Pines, A [1 ]
机构
[1] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94550 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(98)00732-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The feasibility of producing supercritical laser-polarized xenon for nuclear magnetic resonance (NMR) investigations was studied. Using a high-pressure capillary tube, a supercritical xenon sample (52 degrees C, 65 atm) was produced with a Xe-129 polarization approximately 140 times the equilibrium value. The polarization was observed to last for hundreds of seconds, in agreement with previous studies. These preliminary results suggest that supercritical laser-polarized xenon may be used as a polarizing solvent for numerous NMR applications. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:686 / 690
页数:5
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