The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds with sulfenate esters

被引：3

作者：

Hall, CD ^{[1
]}

Tweedy, BR ^{[1
]}

Lowther, N ^{[1
]}

机构：

[1] Univ London Kings Coll, Dept Chem, London WC2R 2LS, England

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 123卷

基金：

英国工程与自然科学研究理事会;

关键词：

tricoordinate phosphorus; sulfenate esters; thiophosphoranes; oxyphosphoranes; kinetics; mechanism;

D O I：

10.1080/10426509708044221

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)(3-n) with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.

引用

页码：341 / 358

页数：18

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