An Octanuclear [Cr4IIIDy4III] 3d-4f Single-Molecule Magnet

被引：247

作者：

Rinck, Julia ^{[1
]}

Novitchi, Ghenadie ^{[1
]}

Van den Heuvel, Willem ^{[2
,3
]}

Ungur, Liviu ^{[2
,3
]}

Lan, Yanhua ^{[1
]}

Wernsdorfer, Wolfgang ^{[4
]}

Anson, Christopher E. ^{[1
]}

Chibotaru, Liviu F. ^{[2
,3
]}

Powell, Annie K. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany

[2] Katholieke Univ Leuven, Div Quantum & Phys Chem, B-3001 Heverlee, Belgium

[3] Katholieke Univ Leuven, INPAC Inst Nanoscale Phys & Chem, B-3001 Heverlee, Belgium

[4] CNRS, Inst Neel, F-38042 Grenoble 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 41期

关键词：

anisotropy; chromium; lanthanides; magnetic properties; single-molecule magnets; MAGNETIZATION; COMPLEXES; DY; TB; LN; MANGANESE; CLUSTERS; BEHAVIOR; DIMERS; LH3;

D O I：

10.1002/anie.201002690

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Square-within-a-square": The first Cr-Dy single-molecule magnet (SMM) with an energy barrier to spin reorientation of 15 K is presented. The anisotropy in this octanuclear compound arises from the orientations of the four DyIII centers (dark blue), which, in conjunction with the contributions from the CrIII centers (green), leads to the SMM behavior. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7583 / 7587

页数：5

共 38 条

[1] Synthesis, structures and magnetic properties of heterometallic Mn2IIILn2III tetranuclear complexes [J].

Akhtar, Muhammad Nadeem ;

Lan, Yanhua ;

Mereacre, Valeriu ;

Clerac, Rodolphe ;

Anson, Christopher E. ;

Powell, Annie K. .

POLYHEDRON, 2009, 28 (9-10) :1698-1703

[2]

ARONICA C, 2006, ANGEW CHEM, V118, P4775

[3] A nonanuclear dysprosium (III)-copper(II) complex exhibiting single-molecule magnet behavior with very slow zero-field relaxation [J].

Aronica, Christophe ;

Pilet, Guillaume ;

Chastanet, Guillaume ;

Wernsdorfer, Wolfgang ;

Jacquot, Jean-Francois ;

Luneau, Dominique .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (28) :4659-4662

[4] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[5] Trinuclear heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4] (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er;: LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3):: From simple paramagnetic complexes to single-molecule magnet behavior [J].

Chandrasekhar, Vadapalli ;

Pandian, Balasubramanian Murugesa ;

Boomishankar, Ramarnoorthy ;

Steiner, Alexander ;

Viftal, Jagadese J. ;

Houri, Ahmad ;

Clerac, Rodolphe .

INORGANIC CHEMISTRY, 2008, 47 (11) :4918-4929

[6] Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3]: A 3d-4f Family of Single-Molecule Magnets [J].

Chandrasekhar, Vadapalli ;

Pandian, Balasubramanian Murugesa ;

Vittal, Jagadese J. ;

Clerac, Rodolphe .

INORGANIC CHEMISTRY, 2009, 48 (03) :1148-1157

[7] Structure, magnetism, and theoretical study of a mixed-valence Co3IICo4III heptanuclear wheel:: Lack of SMM behavior despite negative magnetic anisotropy [J].

Chibotaru, Liviu F. ;

Ungur, Liviu ;

Aronica, Christophe ;

Elmoll, Hani ;

Pilet, Guillaume ;

Luneau, Dominique .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) :12445-12455

[8] Single-molecule magnets [J].

Christou, George ;

Gatteschi, Dante ;

Hendrickson, David N. ;

Sessoli, Roberta .

MRS Bulletin, 2000, 25 (11) :66-71

[9] Dispersion and absorption in dielectrics I. Alternating current characteristics [J].

Cole, KS ;

Cole, RH .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) :341-351

[10] Heterodinuclear Cu-Tb single-molecule magnet [J].

Costes, JP ;

Dahan, F ;

Wernsdorfer, W .

INORGANIC CHEMISTRY, 2006, 45 (01) :5-7

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