Role of oxygen transients in the facile scission of C-O bonds of alcohols on Zn surfaces

被引:7
作者
Harikumar, KR
Rao, CNR [1 ]
机构
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, CSIR, Ctr Excellence Chem, Bangalore 560012, Karnataka, India
关键词
D O I
10.1039/a808076c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The alkoxy species produced by the interaction of alcohols with Zn surfaces undergoes C-O bond scission at 150 K giving hydrocarbon species, but this transformation occurs even at 80 K when alcohol-oxygen mixtures are coadsorbed, due to the oxygen transients.
引用
收藏
页码:341 / 342
页数:2
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