Gas dynamics in channels of a gas-feed direct methanol fuel cell: exact solutions

被引:23
作者
Kulikovsky, AA [1 ]
机构
[1] Forschungszentrum Julich, Inst Mat & Proc Energy Syst IWV3, D-52425 Julich, Germany
关键词
PEFC; DMFC; channels; gas dynamics; modeling;
D O I
10.1016/S1388-2481(01)00216-8
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The gas dynamics in channels on both sides of a gas-feed direct methanol fuel cell (DFMC) are considered. The basic equations for the flow velocity and density are derived, taking into account the mass and momentum transfer through the channel/backing layer interface. For the practical case of small inlet velocities the analog of the Bernoulli equation is formulated and the exact solution of nonlinear gas dynamics equations is obtained. It is shown that the flow in both the cathode and anode channels is incompressible (its density is constant) and electrochemical reactions affect only the flow velocity v. Simple formulae for v, as a function of local current density and effective water drag coefficient are derived. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:572 / 579
页数:8
相关论文
共 27 条
[1]   A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].
BERNARDI, DM ;
VERBRUGGE, MW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2477-2491
[2]   MATHEMATICAL-MODEL OF A GAS-DIFFUSION ELECTRODE BONDED TO A POLYMER ELECTROLYTE [J].
BERNARDI, DM ;
VERBRUGGE, MW .
AICHE JOURNAL, 1991, 37 (08) :1151-1163
[3]   Mathematical model of the PEMFC [J].
Dannenberg, K ;
Ekdunge, P ;
Lindbergh, G .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (12) :1377-1387
[4]   The current voltage plot of PEM fuel cell with long feed channels [J].
Dohle, H ;
Kornyshev, AA ;
Kulikovsky, AA ;
Mergel, J ;
Stolten, D .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (02) :73-80
[5]   Three-dimensional numerical simulation of straight channel PEM fuel cells [J].
Dutta, S ;
Shimpalee, S ;
Van Zee, JW .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (02) :135-146
[6]   Two-dimensional finite-element method study of the resistance of membranes in polymer electrolyte fuel cells [J].
Futerko, P ;
Hsing, IM .
ELECTROCHIMICA ACTA, 2000, 45 (11) :1741-1751
[7]   Modelling of performance of PEM fuel cells with conventional and interdigitated flow fields [J].
Kazim, A ;
Liu, HT ;
Forges, P .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1999, 29 (12) :1409-1416
[8]  
KORNYSHEV AA, 2001, IN PRESS ELECTROCHIM
[9]   Two-dimensional simulation of direct methanol fuel cell - A new (embedded) type of current collector [J].
Kulikovsky, AA ;
Divisek, J ;
Kornyshev, AA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (03) :953-959
[10]   Modeling the cathode compartment of polymer electrolyte fuel cells: Dead and active reaction zones [J].
Kulikovsky, AA ;
Divisek, J ;
Kornyshev, AA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (11) :3981-3991