Aufbau synthesis of a mixed-metal anion receptor cage

被引：40

作者：

Vilar, R ^{[1
]}

Mingos, DMP ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 03期

关键词：

D O I：

10.1039/a808303g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isolation and structural characterisation of square planar [Ni(atu)(2)] (Hatu = amidinothiourea) has provided a rational basis to synthesise the novel mixed-metal cage compounds [Ni4Pd2(atu)(8)X]X-3 (X = Cl, Br); one of these cages (when X = Cl) has been crystallographically characterised showing that the chloride anion is encapsulated in the centre of the cage forming eight hydrogen-bonds with N-H groups from the ligands and two Lewis acid-base interactions with two palladium(II) ions.

引用

页码：229 / 230

页数：2

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