Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes

被引：251

作者：

Cai, CX

Amgoune, A

Lehmann, CW

Carpentier, JF ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim Rennes, CNRS, UMR 6509, F-35042 Rennes, France

[2] Max Planck Inst Kohlenforsch, D-45466 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 03期

关键词：

D O I：

10.1039/b314030j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymerization of racemic lactide initated by alkyl- and amidoyttrium complexes of a non-chiral tetradentate alkoxy-aminobis(phenolate) ligand proceeds rapidly, in a controlled manner, to give heterotactic-rich polylactic acid.

引用

页码：330 / 331

页数：2

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