Trimethylsilyl trifluoromethanesulfonate catalyzed one-pot method for the conversion of aldehydes to homoallyl ethers in an ionic liquid

被引:11
作者
Anzalone, PW [1 ]
Mohan, RS [1 ]
机构
[1] Illinois Wesleyan Univ, Dept Chem, Lab Environm Friendly Organ Synth, Bloomington, IL 61701 USA
来源
SYNTHESIS-STUTTGART | 2005年 / 16期
关键词
ionic liquids; homoallyl ethers; aldehydes; allylations;
D O I
10.1055/s-2005-872112
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mild method for the trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed one-pot synthesis of homoallyl ethers from aldehydes has been developed in the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([bmim] [OTf]). The advantages of this method include the use of a recyclable ionic liquid, facile product isolation without employing excess organic solvent, elimination of an aqueous waste stream, and mild reaction conditions.
引用
收藏
页码:2661 / 2663
页数:3
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