Catalytic coupling of carbon dioxide and 2,3-epoxy-1,2,3,4-tetrahydronaphthalene in the presence of a (Salen)CrIIICl derivative

被引：51

作者：

Darensbourg, DJ ^{[1
]}

Fang, CC ^{[1
]}

Rodgers, JL ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 04期

关键词：

D O I：

10.1021/om034278m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coupling reaction of carbon dioxide and 2,3-epoxy-1,2,3,4-tetrahydronaphthalene catalyzed by (salen)(CrCl)-Cl-III, H(2)salen = N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediimine, in the presence of a co-catalyst, N-methylimidazole, affords a moderate yield of the cis cyclic carbonate product along with a trace quantity of polycarbonate. The solid-state structures of both the epoxide monomer and the cis cyclic carbonate were determined by X-ray crystallography.

引用

页码：924 / 927

页数：4

共 28 条

[1] SOLUTION CHEMISTRY OF THE SYN-TETRAHYDRODIOL AND ANTI-TETRAHYDRODIOL EPOXIDES, THE SYN-TETRAHYDRODIMETHOXY AND ANTI-TETRAHYDRODIMETHOXY EPOXIDES, AND THE 1,2-TETRAHYDRO EPOXIDES AND 1,4-TETRAHYDRO EPOXIDES OF NAPHTHALENE [J].

BECKER, AR ;

JANUSZ, JM ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (19) :5679-5687

[2] Polymer synthesis - Making polymers from carbon dioxide [J].

Beckman, EJ .

SCIENCE, 1999, 283 (5404) :946-947

[3] Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides:: Catalyst synthesis and unprecedented polymerization activity [J].

Cheng, M ;

Moore, DR ;

Reczek, JJ ;

Chamberlain, BM ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8738-8749

[4] Enantiomerically-enriched organic reagents via polymer synthesis:: enantioselective copolymerization of cycloalkene oxides and CO2 using homogeneous, zinc-based catalysts [J].

Cheng, M ;

Darling, NA ;

Lobkovsky, EB ;

Coates, GW .

CHEMICAL COMMUNICATIONS, 2000, (20) :2007-2008

[5] Catalytic reactions involving C1 feedstocks:: New high-activity Zn(II)-based catalysts for the alternating copolymerization of carbon dioxide and epoxides [J].

Cheng, M ;

Lobkovsky, EB ;

Coates, GW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) :11018-11019

[6] The copolymerization of carbon dioxide and [2-(3,4-epoxycyclohexyl)ethyl]trimethoxysI lane catalyzed by (salen)CrCl. : Formation of a CO2 soluble polycarbonate [J].

Darensbourg, DJ ;

Rodgers, JL ;

Fang, CC .

INORGANIC CHEMISTRY, 2003, 42 (15) :4498-4500

[7] Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copolymer vs cyclic carbonate production [J].

Darensbourg, DJ ;

Yarbrough, JC ;

Ortiz, C ;

Fang, CC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (25) :7586-7591

[8] Carbon dioxide/epoxide coupling reactions utilizing lewis base adducts of zinc halides as catalysts. Cyclic carbonate versus polycarbonate production [J].

Darensbourg, DJ ;

Lewis, SJ ;

Rodgers, JL ;

Yarbrough, JC .

INORGANIC CHEMISTRY, 2003, 42 (02) :581-589

[9] Catalytic activity of a series of Zn(II) phenoxides for the copolymerization of epoxides and carbon dioxide [J].

Darensbourg, DJ ;

Holtcamp, MW ;

Struck, GE ;

Zimmer, MS ;

Niezgoda, SA ;

Rainey, P ;

Robertson, JB ;

Draper, JD ;

Reibenspies, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) :107-116

[10] Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst [J].

Darensbourg, DJ ;

Yarbrough, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6335-6342

← 1 2 3 →