Highly effective epoxidation of alkenes with Ti-containing soluble polymers

被引：7

作者：

Blanco-Brieva, G

Campos-Martín, JM

de Frutos, MP

Fierro, JLG

机构：

[1] CSIC, Inst Catalisis & Petroleoquim, Madrid 28049, Spain

[2] Repsol YPF, Ctr Invest & Desarrollo, Madrid 28045, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b105362k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ti-containing polysiloxane epoxidation catalysts have been prepared by controlled hydrolysis of titanium- and alkylsilane precursors. These polysiloxanes exhibit very high yields to epoxides in the epoxidation reaction of primary alkenes with organic hydroperoxides.

引用

页码：2228 / 2229

页数：2

共 21 条

[1]

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[2]

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