Spray processable green to highly transmissive electrochromics via chemically polymerizable donor-acceptor heterocyclic pentamers

被引:162
作者
Beaujuge, Pierre M. [1 ]
Ellinger, Stefan [1 ]
Reynolds, John R. [1 ]
机构
[1] Univ Florida, Ctr Macromol Sci & Engn, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
关键词
D O I
10.1002/adma.200800280
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochromic polymers (ECPs) of tunable green: Two symmetrical donoracceptor based oligomers were designed, synthesized and chemically polymerized affording solutionprocessable conjugated polymers of distinct green hues in their neutral state. The polyheterocyclic hybrids exhibited highly transmissive oxidized states, excellent optical contrasts both in the visible and in the near infrared, fast switching times and long-term redox switching stability as expected for practical ECP devices.
引用
收藏
页码:2772 / +
页数:6
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