CeO2 doped SnO2 sensor selective to ethanol in presence of CO, LPG and CH4

被引:133
作者
Pourfayaz, F
Khodadadi, A
Mortazavi, Y
Mohajerzadeh, SS
机构
[1] Univ Tehran, Dept Chem Engn, Tehran, Iran
[2] Univ Tehran, Dept Elect & Comp Engn, Tehran, Iran
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2005年 / 108卷 / 1-2期
关键词
gas sensor; semiconductor; ethanol sensor; ceria; tin oxide;
D O I
10.1016/j.snb.2004.12.107
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present study, the sensitivity of SnO2 and CeO2/SnO2 sensors to ethanol in the presence of CO, LPG and CH4 gases were examined. SnO2 andCeO(2)/SnO2 were prepared by a sol-gel method and sintered at 600 and 800 degrees C. As SnO2 is doped with 2.0 wt.% ceria, at 300 degrees C, the sensitivity to ethanol with respect to methane, LPG and CO is enhanced by factors of about 5.3, 48.2 and 5.2, respectively. As the temperature is increased to 350 degrees C, the ceria-doped SnO2 becomes more sensitive to CO and LPG. The results revealed that, for all gases, the sensitivity of the sensors sintered at 600 degrees C was higher than the ones sintered at 800 degrees C, however, the effect was much more pronounced with regards to ethanol. In addition, doping the SnO2 sensor with CeO2 reduces the long recovery time observed for pure SnO2 sensor in presence of ethanol. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:172 / 176
页数:5
相关论文
共 13 条
[1]   Sol-gel derived pure and palladium activated tin oxide films for gas-sensing applications [J].
De, G ;
Licciulli, A ;
Massaro, C ;
Quirini, A ;
Rella, R ;
Siciliano, P ;
Vasanelli, L .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 55 (2-3) :134-139
[2]   Room temperature H2S sensing properties and mechanism of CeO2-SnO2 sol-gel thin films [J].
Fang, GJ ;
Liu, ZL ;
Liu, CQ ;
Yao, KL .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 66 (1-3) :46-48
[3]   Electrical properties evolution under reducing gaseous mixtures (H2, H2S, CO) of SnO2 thin films doped with Pd/Pt aggregates and used as polluting gas sensors [J].
Gaidi, M ;
Chenevier, B ;
Labeau, M .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 62 (01) :43-48
[4]   H2 selective gas sensor based on SnO2 [J].
Katsuki, A ;
Fukui, K .
SENSORS AND ACTUATORS B-CHEMICAL, 1998, 52 (1-2) :30-37
[5]   Cerium oxide/SnO2-based semiconductor gas sensors with improved sensitivity to CO [J].
Khodadadi, A ;
Mohajerzadeh, SS ;
Mortazavi, Y ;
Miri, AM .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 80 (03) :267-271
[6]   CO2-sensing characteristics of SnO2 thick film by coating lanthanum oxide [J].
Kim, DH ;
Yoon, JY ;
Park, HC ;
Kim, KH .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 62 (01) :61-66
[7]   Relationships between sensitivity, catalytic activity, and surface areas of SnO gas sensors [J].
Li, GJ ;
Zhang, XH ;
Kawi, S .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 60 (01) :64-70
[8]   Preparation of SnO2 films with high sensitivity and selectivity to C2H5OH by oxygen radical assisted electron beam evaporation for micro-machined gas sensors [J].
Mo, YW ;
Okawa, Y ;
Nakai, T ;
Tajima, M ;
Natukawa, K .
THIN SOLID FILMS, 2002, 416 (1-2) :248-253
[9]   Air quality monitoring by means of sol-gel integrated tin oxide thin films [J].
Rella, R ;
Siciliano, P ;
Capone, S ;
Epifani, M ;
Vasanelli, L ;
Licciulli, A .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 58 (1-3) :283-288
[10]  
XINGHUI W, 2002, MATER CHEM PHYS, V77, P588