Synthesis and characterization of porous and nonporous monodisperse colloidal TiO2 particles

被引：211

作者：

Eiden-Assmann, S ^{[1
]}

Widoniak, J ^{[1
]}

Maret, G ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Phys, D-78457 Constance, Germany

来源：

CHEMISTRY OF MATERIALS | 2004年 / 16卷 / 01期

关键词：

D O I：

10.1021/cm0348949

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Monodisperse spherical titania particles of variable sizes are produced in a sol-gel synthesis from Ti(EtO)(4) in ethanol with addition of a salt or a polymer solution. The influence of different salt ions or polymer molecules on the size and the size distribution of the final particles was investigated. The amorphous hydrous titania particles were characterized by electron microscopy, thermogravimetry, H-1-MAS NMR, X-ray absorption spectroscopy, and electrophoresis. Nitrogen absorption measurements revealed that the addition of polymers yields hollow and porous titania colloids.

引用

页码：6 / 11

页数：6

共 20 条

[1] BARRINGER EA, 1982, J AM CERAM SOC, V65, P199
[2] A XANES AND EXAFS INVESTIGATION OF TITANIUM SILICALITE
BEHRENS, P
FELSCHE, J
VETTER, S
SCHULZEKLOFF, G
JAEGER, NI
NIEMANN, W
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (10) : 678 - 680
[3] Birner A., 1999, PHYS BL, V55, P27
[4] STUDIES OF THE KINETICS OF THE PRECIPITATION OF UNIFORM SILICA PARTICLES THROUGH THE HYDROLYSIS AND CONDENSATION OF SILICON ALKOXIDES
BOGUSH, GH
ZUKOSKI, CF
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1991, 142 (01) : 1 - 18
[5] ROLE OF PARTICLE SUBSTRUCTURE IN THE SINTERING OF MONOSIZED TITANIA
EDELSON, LH
GLAESER, AM
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (04) : 225 - 235
[6] Preparation and characterization of hollow spheres of rutile
Eiden, S
Maret, G
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 250 (02) : 281 - 284
[7] PAPER WHITENERS .1. TITANIA COATED SILICA
HSU, WP
YU, RC
MATIJEVIC, E
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1993, 156 (01) : 56 - 65
[8] Preparation and characterization of titania-coated polystyrene spheres and hollow titania shells
Imhof, A
[J]. LANGMUIR, 2001, 17 (12) : 3579 - 3585
[9] Fabrication of hollow polystyrene nanospheres in microemulsion polymerization using triblock copolymers
Jang, J
Ha, H
[J]. LANGMUIR, 2002, 18 (14) : 5613 - 5618
[10] NUCLEATION AND GROWTH OF MONOSIZED TIO2 POWDERS FROM ALCOHOL SOLUTION
JEAN, JH
RING, TA
[J]. LANGMUIR, 1986, 2 (02) : 251 - 255

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