Rational design of an enneanuclear copper(II) complex with a metallacyclophane core

被引：56

作者：

Ottenwaelder, X

Cano, J

Journaux, Y ^{[1
]}

Rivière, E

Brennan, C

Nierlich, M

Ruiz-García, R

机构：

[1] Univ Paris 11, Chim Inorgan Lab, CNRS, UMR 8613, F-91405 Orsay, France

[2] Ctr Etud Saclay, DRECAM, DSM, Serv Chim Mol,CEA, F-91191 Gif Sur Yvette, France

[3] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Valencia, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 07期

关键词：

copper; cyclophanes; magnetic properties; metallacycles; N; O ligands; nonanuclear complex;

D O I：

10.1002/anie.200352851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hexakis-bidentate building block: Tri-copper(II) and enneacopper(II) 1,3,5-metallacyclophanes were synthesized by a combination of self-assembly and a rational approach (see scheme). Both complexes exhibit ferromagnetic coupling in the core, through a spin-polarization mechanism.

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页码：850 / 852

页数：3

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