Formation of water clusters in a hydrophobic solvent

被引：68

作者：

Köddermann, T ^{[1
]}

Schulte, F ^{[1
]}

Huelsekopf, M ^{[1
]}

Ludwig, R ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 40期

关键词：

cluster compounds; hydrogen bonds; IR spectroscopy; water chemistry;

D O I：

10.1002/anie.200351438

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

And not a drop to drink: Hydrogen-bonded water clusters could be detected in CCl4 by IR spectroscopy. The comparison between measured and calculated frequencies along with the characteristic temperature behavior of band intensities suggests that cyclic clusters are formed up to the tetramer (see picture).

引用

页码：4904 / 4908

页数：5

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