Processability, morphology and mechanical properties of glass fiber reinforced poly(ether sulfone) modified by a liquid crystalline copolyester

Ternary composites based on glass fiber reinforced polyethersulfone (gPES) modified by a liquid crystalline copolyester (R5) were obtained by injection molding at different nozzle temperatures and at LCP contents up to 20%. The blends showed two pure amorphous phases. The ability of R5 to improve processing was seen mainly in the increase in the MFI of the blends on 5% LCP addition, which was more than 75% and 16% with respect to that of pure gPES and PES, respectively. The best processing temperature appeared to be 330degreesC, as it led to the maximum skin fibrillation and provided both the best small strain and fracture mechanical properties. The blend processed at 330degreesC with 5% R5 showed the best balance of properties because, besides the highest relative processability increase, it led to maximum values in all mechanical properties measured. This was due to both the overall fibrillation of the skin and to its having the highest ductility.